Synthesis of some oxadiazole derivatives of d‐mannose

The syntheses of 2‐methyl‐5‐[1′,2′,3′,4′,5′‐penta‐O‐benzoyl‐D‐manno‐pentitol‐1′‐yl]‐1,3,4‐oxadiazole and 5‐methyl‐3‐[1′,2′,3′,4′,5′‐penta‐O‐benzoyl‐D‐manno‐pentitol‐1‐′yl]‐1,2,4‐oxadiazole, as well as their intermediate products, are described. Their 1H and 13C nmr and ms spectra are presented and t...

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Autores principales: Fascio, M.L., D'Accorso, N.B.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_0022152X_v32_n3_p815_Fascio
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Sumario:The syntheses of 2‐methyl‐5‐[1′,2′,3′,4′,5′‐penta‐O‐benzoyl‐D‐manno‐pentitol‐1′‐yl]‐1,3,4‐oxadiazole and 5‐methyl‐3‐[1′,2′,3′,4′,5′‐penta‐O‐benzoyl‐D‐manno‐pentitol‐1‐′yl]‐1,2,4‐oxadiazole, as well as their intermediate products, are described. Their 1H and 13C nmr and ms spectra are presented and their preferential conformation in solution are proposed. Copyright © 1995 Journal of Heterocyclic Chemistry