Coordinated nitroxyl anion is produced and released as nitrous oxide by the decomposition of iridium-coordinated nitrosothiols
The aqueous decomposition of the iridium coordinated nitrosothiols (RSNOs) trans-K[IrCl4(CH3CN)NOSPh] (1), and K 2[IrCl5(NOECyS)] (2, ECyS = cysteine ethyl ester), was studied by MS analysis of the gaseous products, ESI-MS, NMR, and UV-Vis spectroscopy. Bent NO (NO-, nitroxyl anion), sulfenic acids...
Guardado en:
| Autores principales: | Kazhdan, D., Perissinotti, L.L., Watanabe, B., Eberlin, M.N., Milagre, H.M.S., Vaz, B.G., Estrin, D.A., Doctorovich, F. |
|---|---|
| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201693_v366_n1_p85_Kazhdan |
| Aporte de: |
Ejemplares similares
-
Coordinated nitroxyl anion is produced and released as nitrous oxide by the decomposition of iridium-coordinated nitrosothiols
Publicado: (2011) -
Synthesis and structural characterisation of unprecedented primary N -nitrosamines coordinated to iridium(IV)
por: Foi, María Ana, et al.
Publicado: (2018) -
NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-
por: Escola, Natalia, et al.
Publicado: (2011) -
NO+, NO•, NO-! Nitrosyl siblings from [IrCl5(NO)]-
por: Escola, N., et al. -
A surprisingly stable S-nitrosothiol complex
por: Perissinotti, L.L., et al.