Metallonitrosyl fragment as electron acceptor: Intramolecular charge transfer, long range electronic coupling, and electrophilic reactivity in the trans-[NCRu(py)4(CN)Ru(py)4NO]3+ Ion
The new complex trans-[NCRu(py)4(CN)Ru(py)4NO] (PF6)3 (I) was synthesized. In acetonitrile solution, I shows an intense visible band (555 nm, ε = 5800 M-1 cm-1) and other absorptions below 350 nm, associated with dπ → π*py and πpy → π*py transitions. The visible band is presently assigned as a donor...
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| Autores principales: | Roncaroli, F., Baraldo, L.M., Slep, L.D., Olabe, J.A. |
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| Formato: | JOUR |
| Materias: | |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v41_n7_p1930_Roncaroli |
| Aporte de: |
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