The mpz+/mpz. Pair as Organic Analogue of the NO+/NO. Ligand Redox System (mpz = N-Methylpyrazinium). A Combined Electrochemical and Spectroscopic Study (UV/Vis/NIR, IR, EPR) of Complexes [(mpz)M(CN)5]2-/3- (M = Fe, Ru, Os)
The oxidation and reduction behavior of complexes [(mpz)M(CN)5]2- between the group 8 pentacyanometalates-(II) and the N-methylpyrazinium ion mpz+ was studied using spectroelectrochemical techniques (UV/vis/NIR, IR, EPR) in nonaqueous and, in part, aqueous media. As a further source of information o...
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Autores principales: | Waldhör, E., Kaim, W., Olabe, J.A., Slep, L.D., Fiedler, J. |
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Formato: | JOUR |
Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00201669_v36_n14_p2969_Waldhor |
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