Effects of the nucleophile structure on the mechanisms of reaction of 1-chloro-2,4-dinitrobenzene with aromatic amines in aprotic solvents

The kinetics of reactions of 1-chloro-2,4-dinitrobenzene with aniline and several substituted aromatic amines, B, in toluene shows a quadratic dependence of the second-order rate constant, kA, on [B], which is preserved even in the presence of increasing amounts of dimethylaniline, while the reactio...

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Autores principales: Nudelman, N.S., Alvaro, C.E.S., Savini, M., Nicotra, V., Yankelevich, J.
Formato: JOUR
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Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00100765_v64_n1_p1583_Nudelman
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