The reaction of ammonia with acetyl derivatives of gentiobiose
The reaction of aqueous ammonia with octa-O-acetylgentiobiose gives 1,1-bis-(acetamido)-1-deoxy-6-O-β-D-glucopyranosyl-D-glucitol (1) and N-acetyl-6-O-β-D-glucopyranosyl-β-D-glucofuranosylamine (3). The structure of the furanoid compound 3 was demonstrated by methylation and hydrolysis techniques, a...
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| Autores principales: | , , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v35_n1_p33_Zanlungo |
| Aporte de: |
| Sumario: | The reaction of aqueous ammonia with octa-O-acetylgentiobiose gives 1,1-bis-(acetamido)-1-deoxy-6-O-β-D-glucopyranosyl-D-glucitol (1) and N-acetyl-6-O-β-D-glucopyranosyl-β-D-glucofuranosylamine (3). The structure of the furanoid compound 3 was demonstrated by methylation and hydrolysis techniques, and its anomeric configuration through periodate oxidation and borohydride reduction. © 1974. |
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