The reaction of ammonia with acylated disaccharides. Part X. Octa-O-benzoyl-lactose and other benzoyl derivatives of lactose

From the reaction of octa-O-benzoyl-lactose (1) with methanolic ammonia, lactose, 1,1-bis(benzamido)-1-deoxy-4-O-β-D-galactopyranosyl-D-glucitol (2), and N-benzoyl-4-O-β-D-galactopyranosyl-D-glucopyranosylamine (3) were obtained. The behavior of some other octabenzoylated disaccharides in the ammono...

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Detalles Bibliográficos
Autores principales: Deferrari, J.O., Thiel, I.M.E., Cadenas, R.A.
Formato: JOUR
Materias:
ammonia
benzoic acid derivative
disaccharide
lactose
methanol
periodic acid
sugar alcohol
article
chemistry
oxidation reduction reaction
paper chromatography
synthesis
technique
Ammonia
Benzoates
Chemistry
Chromatography, Paper
Disaccharides
Lactose
Methanol
Methods
Oxidation-Reduction
Periodic Acid
Sugar Alcohols
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00086215_v29_n1_p141_Deferrari
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:From the reaction of octa-O-benzoyl-lactose (1) with methanolic ammonia, lactose, 1,1-bis(benzamido)-1-deoxy-4-O-β-D-galactopyranosyl-D-glucitol (2), and N-benzoyl-4-O-β-D-galactopyranosyl-D-glucopyranosylamine (3) were obtained. The behavior of some other octabenzoylated disaccharides in the ammonolysis reaction is discussed. © 1973.

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