The reaction of penta-O-nicotinoyl-α-D-glucopyranose with aqueous ammonia
Penta-O-nicotinoyl-α-D-glucopyranose reacts with aqueous ammonia to yield N-nicotinoyl-D-glucofuranosylamine, 1-deoxy-1,1-bis(nicotinamido)-D-glucitol, and 2-(D-arabino-tetrahydroxybutyl)-6-(D-erythro-2,3,4-trihydroxybutyl)pyrazine. The structure of these compounds was ascertained by use of oxidatio...
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| Autores principales: | , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v23_n1_p111_Forlano |
| Aporte de: |
| Sumario: | Penta-O-nicotinoyl-α-D-glucopyranose reacts with aqueous ammonia to yield N-nicotinoyl-D-glucofuranosylamine, 1-deoxy-1,1-bis(nicotinamido)-D-glucitol, and 2-(D-arabino-tetrahydroxybutyl)-6-(D-erythro-2,3,4-trihydroxybutyl)pyrazine. The structure of these compounds was ascertained by use of oxidation techniques and spectroscopic data. The formation of the pyrazine compound is discussed. © 1972. |
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