Confirmation of the structures of the products obtained on acylation of 2-amino-2-deoxy-d-gluconic acid

Acetylation of 2-amino-2-deoxy-d-gluconic acid (1) with acetyl chloride-pyridine gave 2,3-unsaturated six- and five-membered lactones (2 and 3). Their benzoylated analogs (4 and 5) were obtained by benzoylation of 1 with benzoyl chloride-pyridine. Reaction of 1 with hot acetic anhydride-sodium aceta...

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Detalles Bibliográficos
Autores principales: Horton, D., Thomson, J.K., Varela, O., Nin, A., de Lederkremer, R.M.
Formato: JOUR
Materias:
benzenecarbonyl chloride
benzoic acid derivative
drug derivative
glucosamine
glucosaminic acid
lactone
acetylation
article
chemical structure
nuclear magnetic resonance spectroscopy
stereoisomerism
synthesis
Acetylation
Benzoates
Glucosamine
Lactones
Magnetic Resonance Spectroscopy
Molecular Structure
Stereoisomerism
Support, Non-U.S. Gov't
Support, U.S. Gov't, P.H.S.
Acceso en línea:http://hdl.handle.net/20.500.12110/paper_00086215_v193_nC_p49_Horton
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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