The formation of N-acylglycosylamines of some monosaccharides. D-mannose and L-rhamnose derivatives
The factors that determine the favored formation of furanoid rings in the N-acylglycosylamines obtained by ammonolysis of O-acyl derivatives of some monosaccharides are discussed. The isolation and structure of N-acetyl-α- and -β-D-mannofuranosylamine, Nacetyl-α-D- mannopyranosylamine, N-acetyl-α-L-...
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| Autores principales: | , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v14_n2_p245_Zanlungo |
| Aporte de: |
| Sumario: | The factors that determine the favored formation of furanoid rings in the N-acylglycosylamines obtained by ammonolysis of O-acyl derivatives of some monosaccharides are discussed. The isolation and structure of N-acetyl-α- and -β-D-mannofuranosylamine, Nacetyl-α-D- mannopyranosylamine, N-acetyl-α-L-rhamnopyranosylamine, and Nacetyl-α-L-rhamnofuranosylamine are reported, and the conformation of the last two compounds is discussed on the basis of data from n.m.r. spectroscopy. © 1970. |
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