Acyl migrations in acylated monosaccharides. Formation of N-acetyl-β-D-galactofuranosylamine
The conformational and steric factors that determine the different contributions of the acyl groups to the formation of 1,1-bis(acylamido)-1-deoxyalditols by the ammonolysis of acyl esters of carbohydrates of different structures are discussed. The isolation and structure of N-acetyl β-D-galactofura...
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| Autores principales: | , , |
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| Formato: | JOUR |
| Acceso en línea: | http://hdl.handle.net/20.500.12110/paper_00086215_v10_n3_p403_BZanlungo |
| Aporte de: |
| Sumario: | The conformational and steric factors that determine the different contributions of the acyl groups to the formation of 1,1-bis(acylamido)-1-deoxyalditols by the ammonolysis of acyl esters of carbohydrates of different structures are discussed. The isolation and structure of N-acetyl β-D-galactofuranosylamine, obtained by such a reaction, are reported, and the conformation of this sugar and that of the N-acetyl-α-D-glucofuranosylamine previously described are considered on the basis of n.m.r. data. © 1969. |
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