Internal asymmetric induction by the C-6 substituent on the oxidation reaction of interglycosidic sulfur atom of thiodisaccharides

Since the enantio or diastereoselective preparation of sulfoxides is a current challenge, we explore the possibility of inducing diastereoselectivity in the oxidation of the sulfur atom of thiodisaccharides, according to their substitution patterns. Thus, a series of 3-deoxy-4-S-(β-d-glucopyranosyl)...

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Detalles Bibliográficos
Publicado:	2017
Materias:	Atoms Chemical shift Oxidation Stereoselectivity Sulfur Absolute configuration Anisotropic effects Asymmetric induction Diastereo-selectivity Diastereoselective Free hydroxyl groups Oxidation reactions Substitution patterns Internal oxidation
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_20462069_v7_n70_p44410_Colomer http://hdl.handle.net/20.500.12110/paper_20462069_v7_n70_p44410_Colomer
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

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