Perfluoroalkylation of alkenes and alkynes in water
Perfluoroalkylation of alkenes and alkynes was performed using thermal initiation by ACCN (1,1′-azobis(cyclohexanecarbonitrile)) in water, with good yields. The procedure is simple and more ecofriendly that most of the methods published for the synthesis of related compounds. Using water (without an...
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2015
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_15517004_v2015_n5_p190_Vazquez http://hdl.handle.net/20.500.12110/paper_15517004_v2015_n5_p190_Vazquez |
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| Sumario: | Perfluoroalkylation of alkenes and alkynes was performed using thermal initiation by ACCN (1,1′-azobis(cyclohexanecarbonitrile)) in water, with good yields. The procedure is simple and more ecofriendly that most of the methods published for the synthesis of related compounds. Using water (without any cosolvent or metal catalysts), it allows the synthesis of the addition products with medium to high yields. ©ARKAT-USA, Inc. |
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