Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions

The title ternary complex has been prepared and its structure determined using X-ray crystallography. The complex crystallizes in triclinic space group P-1 with a = 6.745(5), b = 10.551(5), c = 11.414(5) Å , α = 95.770(5), β = 91.396(5), γ = 92.518(5)°, V = 807.1 Å 3 and Z = 2. The structural data a...

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Guardado en:
Detalles Bibliográficos
Publicado: 2012
Materias:
π-π Interactions
Crystal structure
H-bonding
Jahn-Teller distortion
Mixed-ligand copper(II) complex
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10741542_v42_n10_p1042_Siddiqi
http://hdl.handle.net/20.500.12110/paper_10741542_v42_n10_p1042_Siddiqi
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_10741542_v42_n10_p1042_Siddiqi
record_format dspace
spelling paper:paper_10741542_v42_n10_p1042_Siddiqi2023-06-08T16:04:59Z Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions π-π Interactions Crystal structure H-bonding Jahn-Teller distortion Mixed-ligand copper(II) complex The title ternary complex has been prepared and its structure determined using X-ray crystallography. The complex crystallizes in triclinic space group P-1 with a = 6.745(5), b = 10.551(5), c = 11.414(5) Å , α = 95.770(5), β = 91.396(5), γ = 92.518(5)°, V = 807.1 Å 3 and Z = 2. The structural data are consistent with the presence of Jahn-Teller distortion in the overall hexacoordinate octahedral geometry of the molecule. The crystal packing is through an extensive hydrogen bonding and ring-ring π-π interactions resulting in a supramolecular framework. © Springer Science+Business Media, LLC 2012. 2012 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10741542_v42_n10_p1042_Siddiqi http://hdl.handle.net/20.500.12110/paper_10741542_v42_n10_p1042_Siddiqi
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic π-π Interactions
Crystal structure
H-bonding
Jahn-Teller distortion
Mixed-ligand copper(II) complex
spellingShingle π-π Interactions
Crystal structure
H-bonding
Jahn-Teller distortion
Mixed-ligand copper(II) complex
Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions
topic_facet π-π Interactions
Crystal structure
H-bonding
Jahn-Teller distortion
Mixed-ligand copper(II) complex
description The title ternary complex has been prepared and its structure determined using X-ray crystallography. The complex crystallizes in triclinic space group P-1 with a = 6.745(5), b = 10.551(5), c = 11.414(5) Å , α = 95.770(5), β = 91.396(5), γ = 92.518(5)°, V = 807.1 Å 3 and Z = 2. The structural data are consistent with the presence of Jahn-Teller distortion in the overall hexacoordinate octahedral geometry of the molecule. The crystal packing is through an extensive hydrogen bonding and ring-ring π-π interactions resulting in a supramolecular framework. © Springer Science+Business Media, LLC 2012.
title Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions
title_short Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions
title_full Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions
title_fullStr Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions
title_full_unstemmed Crystal structure of a mixed-ligand Cu(II) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions
title_sort crystal structure of a mixed-ligand cu(ii) complex forming supramolecular assembly via an extensive h-bonding and ring-ring π-π interactions
publishDate 2012
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_10741542_v42_n10_p1042_Siddiqi
http://hdl.handle.net/20.500.12110/paper_10741542_v42_n10_p1042_Siddiqi
_version_ 1768544461831274496

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