A highly convenient new methodology for the synthesis of N-nitrosamines from lithium amides
N-nitrosoalkylamines were efficiently synthesized from the reaction of lithium amides with NO at atmospheric pressure using dialkylamines as starting materials. With asymmetric amines stereoselectivity is observed giving rise to different amounts of E and Z isomers.
Guardado en:
| Publicado: |
2000
|
|---|---|
| Materias: | |
| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09365214_v_n12_p1825_Nudelman http://hdl.handle.net/20.500.12110/paper_09365214_v_n12_p1825_Nudelman |
| Aporte de: |
| Sumario: | N-nitrosoalkylamines were efficiently synthesized from the reaction of lithium amides with NO at atmospheric pressure using dialkylamines as starting materials. With asymmetric amines stereoselectivity is observed giving rise to different amounts of E and Z isomers. |
|---|