Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions
In the present work, the kinetic toluene oxidation on VSb0.8Ti0.2O4 based catalyst was studied. A reaction network, which involves three steps: the partial oxidation of toluene to benzaldehyde, a consecutive oxidation of benzaldehyde to carbon oxides and a parallel oxidation of toluene to carbon oxi...
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2001
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v64_n3-4_p179_Larrondo http://hdl.handle.net/20.500.12110/paper_09205861_v64_n3-4_p179_Larrondo |
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paper:paper_09205861_v64_n3-4_p179_Larrondo2023-06-08T15:50:13Z Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions Activation energy Aldehydes Catalysts Oxidation Reaction kinetics Redox reactions Thermal effects Vanadium compounds Benzaldehyde Vanadium antimonate Toluene In the present work, the kinetic toluene oxidation on VSb0.8Ti0.2O4 based catalyst was studied. A reaction network, which involves three steps: the partial oxidation of toluene to benzaldehyde, a consecutive oxidation of benzaldehyde to carbon oxides and a parallel oxidation of toluene to carbon oxides, was proposed. The kinetic parameters were estimated assuming the redox mechanism proposed by Mars and van Krevelen. The products distribution was strongly affected by the reaction temperature. The adjustment of activation energies for total and partial oxidation of toluene led to the same values. The activation energy for the benzaldehyde oxidation was lower than the one for its formation. 2001 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v64_n3-4_p179_Larrondo http://hdl.handle.net/20.500.12110/paper_09205861_v64_n3-4_p179_Larrondo |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Activation energy Aldehydes Catalysts Oxidation Reaction kinetics Redox reactions Thermal effects Vanadium compounds Benzaldehyde Vanadium antimonate Toluene |
spellingShingle |
Activation energy Aldehydes Catalysts Oxidation Reaction kinetics Redox reactions Thermal effects Vanadium compounds Benzaldehyde Vanadium antimonate Toluene Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions |
topic_facet |
Activation energy Aldehydes Catalysts Oxidation Reaction kinetics Redox reactions Thermal effects Vanadium compounds Benzaldehyde Vanadium antimonate Toluene |
description |
In the present work, the kinetic toluene oxidation on VSb0.8Ti0.2O4 based catalyst was studied. A reaction network, which involves three steps: the partial oxidation of toluene to benzaldehyde, a consecutive oxidation of benzaldehyde to carbon oxides and a parallel oxidation of toluene to carbon oxides, was proposed. The kinetic parameters were estimated assuming the redox mechanism proposed by Mars and van Krevelen. The products distribution was strongly affected by the reaction temperature. The adjustment of activation energies for total and partial oxidation of toluene led to the same values. The activation energy for the benzaldehyde oxidation was lower than the one for its formation. |
title |
Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions |
title_short |
Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions |
title_full |
Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions |
title_fullStr |
Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions |
title_full_unstemmed |
Oxidation of toluene to benzaldehyde over VSb0.8Ti0.2O4. Effect of the operating conditions |
title_sort |
oxidation of toluene to benzaldehyde over vsb0.8ti0.2o4. effect of the operating conditions |
publishDate |
2001 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v64_n3-4_p179_Larrondo http://hdl.handle.net/20.500.12110/paper_09205861_v64_n3-4_p179_Larrondo |
_version_ |
1768545099518574592 |