Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering
A detailed polarization modulation infrared reflection absorption spectroscopy, scanning tunneling microscopy, and electrochemical study on methylene blue (MB) incorporation into alkanethiolate self-assembled monolayers (SAMs) on Au(111) is reported. Results show that the amount of MB incorporated i...
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paper:paper_07437463_v26_n11_p8226_Grumelli2023-06-08T15:44:56Z Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering Grumelli, Doris E. Mendez De Leo, Lucila Paula Bonazzola, Cecilia Calvo, Ernesto Julio Alkanethiolates Alkanethiols Au(1 1 1 ) Electrochemical studies Hydrocarbon chain length Hydrocarbon chains Methylene blue Molecular sensing Polarization modulation infrared reflection absorption spectroscopy Sams Hydrocarbons Infrared spectroscopy Organic polymers Scanning tunneling microscopy Self assembled monolayers Absorption spectroscopy gold hydrocarbon methylene blue article chemistry electrochemistry infrared spectroscopy Electrochemistry Gold Hydrocarbons Methylene Blue Spectroscopy, Fourier Transform Infrared A detailed polarization modulation infrared reflection absorption spectroscopy, scanning tunneling microscopy, and electrochemical study on methylene blue (MB) incorporation into alkanethiolate self-assembled monolayers (SAMs) on Au(111) is reported. Results show that the amount of MB incorporated in the SAMs reaches a maximum for intermediate hydrocarbon chain lengths (C10-C12). Well-ordered SAMs of long alkanethiols (C > C12) hinder the incorporation of the MB molecules into the SAM. On the other hand, less ordered SAMs of short alkanethiols (C ≤ C6) are not efficient to retain the MB incorporated through the defects. For C12 the amount of incorporated MB increases as the SAM disorder is increased. This information is essential to the design of efficient thiol-based Au vectors for transport and delivery of molecules as well as thiol-based Au devices for molecular sensing. © 2010 American Chemical Society. Fil:Grumelli, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Méndez De Leo, L.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bonazzola, C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Calvo, E.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2010 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v26_n11_p8226_Grumelli http://hdl.handle.net/20.500.12110/paper_07437463_v26_n11_p8226_Grumelli |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Alkanethiolates Alkanethiols Au(1 1 1 ) Electrochemical studies Hydrocarbon chain length Hydrocarbon chains Methylene blue Molecular sensing Polarization modulation infrared reflection absorption spectroscopy Sams Hydrocarbons Infrared spectroscopy Organic polymers Scanning tunneling microscopy Self assembled monolayers Absorption spectroscopy gold hydrocarbon methylene blue article chemistry electrochemistry infrared spectroscopy Electrochemistry Gold Hydrocarbons Methylene Blue Spectroscopy, Fourier Transform Infrared |
spellingShingle |
Alkanethiolates Alkanethiols Au(1 1 1 ) Electrochemical studies Hydrocarbon chain length Hydrocarbon chains Methylene blue Molecular sensing Polarization modulation infrared reflection absorption spectroscopy Sams Hydrocarbons Infrared spectroscopy Organic polymers Scanning tunneling microscopy Self assembled monolayers Absorption spectroscopy gold hydrocarbon methylene blue article chemistry electrochemistry infrared spectroscopy Electrochemistry Gold Hydrocarbons Methylene Blue Spectroscopy, Fourier Transform Infrared Grumelli, Doris E. Mendez De Leo, Lucila Paula Bonazzola, Cecilia Calvo, Ernesto Julio Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering |
topic_facet |
Alkanethiolates Alkanethiols Au(1 1 1 ) Electrochemical studies Hydrocarbon chain length Hydrocarbon chains Methylene blue Molecular sensing Polarization modulation infrared reflection absorption spectroscopy Sams Hydrocarbons Infrared spectroscopy Organic polymers Scanning tunneling microscopy Self assembled monolayers Absorption spectroscopy gold hydrocarbon methylene blue article chemistry electrochemistry infrared spectroscopy Electrochemistry Gold Hydrocarbons Methylene Blue Spectroscopy, Fourier Transform Infrared |
description |
A detailed polarization modulation infrared reflection absorption spectroscopy, scanning tunneling microscopy, and electrochemical study on methylene blue (MB) incorporation into alkanethiolate self-assembled monolayers (SAMs) on Au(111) is reported. Results show that the amount of MB incorporated in the SAMs reaches a maximum for intermediate hydrocarbon chain lengths (C10-C12). Well-ordered SAMs of long alkanethiols (C > C12) hinder the incorporation of the MB molecules into the SAM. On the other hand, less ordered SAMs of short alkanethiols (C ≤ C6) are not efficient to retain the MB incorporated through the defects. For C12 the amount of incorporated MB increases as the SAM disorder is increased. This information is essential to the design of efficient thiol-based Au vectors for transport and delivery of molecules as well as thiol-based Au devices for molecular sensing. © 2010 American Chemical Society. |
author |
Grumelli, Doris E. Mendez De Leo, Lucila Paula Bonazzola, Cecilia Calvo, Ernesto Julio |
author_facet |
Grumelli, Doris E. Mendez De Leo, Lucila Paula Bonazzola, Cecilia Calvo, Ernesto Julio |
author_sort |
Grumelli, Doris E. |
title |
Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering |
title_short |
Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering |
title_full |
Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering |
title_fullStr |
Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering |
title_full_unstemmed |
Methylene blue incorporation into alkanethiol SAMs on Au(111): Effect of hydrocarbon chain ordering |
title_sort |
methylene blue incorporation into alkanethiol sams on au(111): effect of hydrocarbon chain ordering |
publishDate |
2010 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07437463_v26_n11_p8226_Grumelli http://hdl.handle.net/20.500.12110/paper_07437463_v26_n11_p8226_Grumelli |
work_keys_str_mv |
AT grumellidorise methyleneblueincorporationintoalkanethiolsamsonau111effectofhydrocarbonchainordering AT mendezdeleolucilapaula methyleneblueincorporationintoalkanethiolsamsonau111effectofhydrocarbonchainordering AT bonazzolacecilia methyleneblueincorporationintoalkanethiolsamsonau111effectofhydrocarbonchainordering AT calvoernestojulio methyleneblueincorporationintoalkanethiolsamsonau111effectofhydrocarbonchainordering |
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1768543280996286464 |