Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes
Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O.
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1999
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n7_p422_Nudelman http://hdl.handle.net/20.500.12110/paper_03082342_v_n7_p422_Nudelman |
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paper:paper_03082342_v_n7_p422_Nudelman |
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paper:paper_03082342_v_n7_p422_Nudelman2025-07-30T18:09:06Z Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes 1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O. 1999 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n7_p422_Nudelman http://hdl.handle.net/20.500.12110/paper_03082342_v_n7_p422_Nudelman |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis |
| spellingShingle |
1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| topic_facet |
1,2 dicarbonyl derivative carbon monoxide ethylene derivative lithium derivative article cis trans isomerism cross linking stereospecificity synthesis |
| description |
Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O. |
| title |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_short |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_full |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_fullStr |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_full_unstemmed |
Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| title_sort |
synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes |
| publishDate |
1999 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03082342_v_n7_p422_Nudelman http://hdl.handle.net/20.500.12110/paper_03082342_v_n7_p422_Nudelman |
| _version_ |
1840320703936593920 |