Photochemical reactions of 2,3-diphenylindoles

The UV irradiation of 2,3-diphenylindoles produces two photochemical reactions: a dehydrocyclization with formation of dibenzocarbazoles and a photo-oxygenation which yields benzophenones. Substituents on the 2,3-diphenylindole have a great influence on the reaction course and in most of the example...

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Detalles Bibliográficos
Autores principales: Mudry, Carlos Alberto, Frasca, Adolfo Rafael
Publicado: 1974
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v30_n17_p2983_Mudry
http://hdl.handle.net/20.500.12110/paper_00404020_v30_n17_p2983_Mudry
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Sumario:The UV irradiation of 2,3-diphenylindoles produces two photochemical reactions: a dehydrocyclization with formation of dibenzocarbazoles and a photo-oxygenation which yields benzophenones. Substituents on the 2,3-diphenylindole have a great influence on the reaction course and in most of the examples here studied only one product was formed. Some considerations about the excited states involved in these reactions are presented. © 1974.