Steroidal derivatives from the roots of mandevilla pentlandiana

The steroids from the roots of Mandevilla pentlandiana were analysed. Six Δ20-steroids and four 6-keto-5α-stanols, novel as natural products, were isolated and characterized by spectroscopic methods. The plant also produces cardenolide glycosides, for which 20-hydroxysterols are known to be biosynth...

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Autores principales: Cabrera, Gabriela Myriam, Palermo, Jorge Alejandro, Seldes, Alicia Marta, Gros, Eduardo Gervasio
Publicado: 1991
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00319422_v30_n4_p1239_Cabrera
http://hdl.handle.net/20.500.12110/paper_00319422_v30_n4_p1239_Cabrera
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Sumario:The steroids from the roots of Mandevilla pentlandiana were analysed. Six Δ20-steroids and four 6-keto-5α-stanols, novel as natural products, were isolated and characterized by spectroscopic methods. The plant also produces cardenolide glycosides, for which 20-hydroxysterols are known to be biosynthetic precursors. The hydroxylated derivatives have not been detected, but Δ20-derivatives, closely related to them, may be involved in that metabolic pathway. © 1991.