Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury

Cobalt and nickel in aqueous solutions can be determined by adsorptive striping voltammetry, using dimethylglyoxime as a complexing agent in order to accumulate the metals efficiently on a mercury surface. In borate buffer solution (pH 9.3) capacity results suggest that Co(II)-dimethylglyoxime (Co(H...

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Detalles Bibliográficos
Autores principales:	Ramirez, Silvana Andrea María, Gordillo, Gabriel Jorge
Publicado:	2002
Materias:	Adsorption Capacitance Cobalt Dimethylglyoxime Mercury electrode Electrochemistry Electrons Mercury (metal) Nickel Reduction Solutions Stripping voltammetry Organic compounds
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v534_n2_p131_Cordon http://hdl.handle.net/20.500.12110/paper_00220728_v534_n2_p131_Cordon
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00220728_v534_n2_p131_Cordon
record_format	dspace
spelling	paper:paper_00220728_v534_n2_p131_Cordon2023-06-08T14:45:24Z Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury Ramirez, Silvana Andrea María Gordillo, Gabriel Jorge Adsorption Capacitance Cobalt Dimethylglyoxime Mercury electrode Adsorption Cobalt Electrochemistry Electrons Mercury (metal) Nickel Reduction Solutions Stripping voltammetry Organic compounds Cobalt and nickel in aqueous solutions can be determined by adsorptive striping voltammetry, using dimethylglyoxime as a complexing agent in order to accumulate the metals efficiently on a mercury surface. In borate buffer solution (pH 9.3) capacity results suggest that Co(II)-dimethylglyoxime (Co(HDMG)2) adsorbs in two different orientations each undergoing different reaction pathways: for low surface concentrations Co(0) is produced and two electrons are transferred; for high surface concentration both Co(II) and the ligand are reduced, this process involving the transfer of more than two electrons. © 2002 Elsevier Science B.V. All rights reserved. Fil:Ramirez, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gordillo, G.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2002 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v534_n2_p131_Cordon http://hdl.handle.net/20.500.12110/paper_00220728_v534_n2_p131_Cordon
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Adsorption Capacitance Cobalt Dimethylglyoxime Mercury electrode Adsorption Cobalt Electrochemistry Electrons Mercury (metal) Nickel Reduction Solutions Stripping voltammetry Organic compounds
spellingShingle	Adsorption Capacitance Cobalt Dimethylglyoxime Mercury electrode Adsorption Cobalt Electrochemistry Electrons Mercury (metal) Nickel Reduction Solutions Stripping voltammetry Organic compounds Ramirez, Silvana Andrea María Gordillo, Gabriel Jorge Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury
topic_facet	Adsorption Capacitance Cobalt Dimethylglyoxime Mercury electrode Adsorption Cobalt Electrochemistry Electrons Mercury (metal) Nickel Reduction Solutions Stripping voltammetry Organic compounds
description	Cobalt and nickel in aqueous solutions can be determined by adsorptive striping voltammetry, using dimethylglyoxime as a complexing agent in order to accumulate the metals efficiently on a mercury surface. In borate buffer solution (pH 9.3) capacity results suggest that Co(II)-dimethylglyoxime (Co(HDMG)2) adsorbs in two different orientations each undergoing different reaction pathways: for low surface concentrations Co(0) is produced and two electrons are transferred; for high surface concentration both Co(II) and the ligand are reduced, this process involving the transfer of more than two electrons. © 2002 Elsevier Science B.V. All rights reserved.
author	Ramirez, Silvana Andrea María Gordillo, Gabriel Jorge
author_facet	Ramirez, Silvana Andrea María Gordillo, Gabriel Jorge
author_sort	Ramirez, Silvana Andrea María
title	Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury
title_short	Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury
title_full	Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury
title_fullStr	Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury
title_full_unstemmed	Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury
title_sort	adsorption and electrochemical reduction of co(ii)-dimethylglyoxime on mercury
publishDate	2002
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v534_n2_p131_Cordon http://hdl.handle.net/20.500.12110/paper_00220728_v534_n2_p131_Cordon
work_keys_str_mv	AT ramirezsilvanaandreamaria adsorptionandelectrochemicalreductionofcoiidimethylglyoximeonmercury AT gordillogabrieljorge adsorptionandelectrochemicalreductionofcoiidimethylglyoximeonmercury
_version_	1768544945283530752

Adsorption and electrochemical reduction of Co(II)-dimethylglyoxime on mercury

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