Remarkable Changes of the Acidity of Bound Nitroxyl (HNO) in the [Ru(Me3[9]aneN3)(L2)(NO)]n+ Family (n = 1-3). Systematic Structural and Chemical Exploration and Bioinorganic Chemistry Implications
This work demonstrates that the acidity of nitroxyl (HNO) coordinated to a metal core is significantly influenced by its coordination environment. The possibility that NO- complexes may be the predominant species in physiological environments has implications in bioinorganic chemistry and biochemist...
Guardado en:
| Publicado: |
2018
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00201669_v57_n19_p12270_Levin http://hdl.handle.net/20.500.12110/paper_00201669_v57_n19_p12270_Levin |
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