Spray-casting ABPBI membranes for high temperature PEM fuel cells

The preparation and characterization of membranes of poly[2,5-benzimidazole] (ABPBI) by spray casting at room temperature from an ethanol solution is described. The prepared membranes doped with 11 M H3PO4 sorbed 1.5 molecules of acid per imidazole ring exhibiting a proton conductivity of 0.05 S · c...

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Autor principal:	Corti, Horacio Roberto
Publicado:	2017
Materias:	Ethanol Ethanolamines Fuel cells Membranes Ethanol solutions Fuel cell tests High temperature pem fuel cells Low temperatures Maximum power density Membrane electrode assemblies Membrane preparation Processability Proton exchange membrane fuel cells (PEMFC)
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v164_n7_pF866_Viva http://hdl.handle.net/20.500.12110/paper_00134651_v164_n7_pF866_Viva
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00134651_v164_n7_pF866_Viva
record_format	dspace
spelling	paper:paper_00134651_v164_n7_pF866_Viva2023-06-08T14:35:44Z Spray-casting ABPBI membranes for high temperature PEM fuel cells Corti, Horacio Roberto Ethanol Ethanolamines Fuel cells Membranes Ethanol solutions Fuel cell tests High temperature pem fuel cells Low temperatures Maximum power density Membrane electrode assemblies Membrane preparation Processability Proton exchange membrane fuel cells (PEMFC) The preparation and characterization of membranes of poly[2,5-benzimidazole] (ABPBI) by spray casting at room temperature from an ethanol solution is described. The prepared membranes doped with 11 M H3PO4 sorbed 1.5 molecules of acid per imidazole ring exhibiting a proton conductivity of 0.05 S · cm−1 at 153◦C. The 80 μm thick, homogeneous, membranes obtained were used for the preparation of a membrane electrode assembly (MEA). Fuel cell test conducted with the prepared MEA at temperatures between 100 and 180◦C shows an increase in the performance with temperature, with a maximum power density of 200 mW · cm−2 at 180◦C. The described ABPBI membrane preparation method from an ethanol solution at low temperature opens a simple route for overcoming the processability problems of the aforementioned polymer. © 2017 The Electrochemical Society. All rights reserved. Fil:Corti, H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2017 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v164_n7_pF866_Viva http://hdl.handle.net/20.500.12110/paper_00134651_v164_n7_pF866_Viva
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Ethanol Ethanolamines Fuel cells Membranes Ethanol solutions Fuel cell tests High temperature pem fuel cells Low temperatures Maximum power density Membrane electrode assemblies Membrane preparation Processability Proton exchange membrane fuel cells (PEMFC)
spellingShingle	Ethanol Ethanolamines Fuel cells Membranes Ethanol solutions Fuel cell tests High temperature pem fuel cells Low temperatures Maximum power density Membrane electrode assemblies Membrane preparation Processability Proton exchange membrane fuel cells (PEMFC) Corti, Horacio Roberto Spray-casting ABPBI membranes for high temperature PEM fuel cells
topic_facet	Ethanol Ethanolamines Fuel cells Membranes Ethanol solutions Fuel cell tests High temperature pem fuel cells Low temperatures Maximum power density Membrane electrode assemblies Membrane preparation Processability Proton exchange membrane fuel cells (PEMFC)
description	The preparation and characterization of membranes of poly[2,5-benzimidazole] (ABPBI) by spray casting at room temperature from an ethanol solution is described. The prepared membranes doped with 11 M H3PO4 sorbed 1.5 molecules of acid per imidazole ring exhibiting a proton conductivity of 0.05 S · cm−1 at 153◦C. The 80 μm thick, homogeneous, membranes obtained were used for the preparation of a membrane electrode assembly (MEA). Fuel cell test conducted with the prepared MEA at temperatures between 100 and 180◦C shows an increase in the performance with temperature, with a maximum power density of 200 mW · cm−2 at 180◦C. The described ABPBI membrane preparation method from an ethanol solution at low temperature opens a simple route for overcoming the processability problems of the aforementioned polymer. © 2017 The Electrochemical Society. All rights reserved.
author	Corti, Horacio Roberto
author_facet	Corti, Horacio Roberto
author_sort	Corti, Horacio Roberto
title	Spray-casting ABPBI membranes for high temperature PEM fuel cells
title_short	Spray-casting ABPBI membranes for high temperature PEM fuel cells
title_full	Spray-casting ABPBI membranes for high temperature PEM fuel cells
title_fullStr	Spray-casting ABPBI membranes for high temperature PEM fuel cells
title_full_unstemmed	Spray-casting ABPBI membranes for high temperature PEM fuel cells
title_sort	spray-casting abpbi membranes for high temperature pem fuel cells
publishDate	2017
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00134651_v164_n7_pF866_Viva http://hdl.handle.net/20.500.12110/paper_00134651_v164_n7_pF866_Viva
work_keys_str_mv	AT cortihoracioroberto spraycastingabpbimembranesforhightemperaturepemfuelcells
_version_	1768542250605740032

Spray-casting ABPBI membranes for high temperature PEM fuel cells

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