Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions
Soft (SS) and hard (HS) stearins obtained from high-oleic high-stearic sunflower oil were isothermally crystallized under dynamic (with agitation) and static conditions at 16, 17, 18, 19, and 20 C and 24, 25, 26, 27, and 28 C, respectively. Both fractions crystallized under the α-form at early stage...
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0003021X_v90_n12_p1773_Martini http://hdl.handle.net/20.500.12110/paper_0003021X_v90_n12_p1773_Martini |
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paper:paper_0003021X_v90_n12_p1773_Martini2023-06-08T14:23:50Z Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions Candal, Roberto Jorge Crystallization Fats High stearic high oleic sunflower oil Morphology Polymorphism Texture Thermal behavior Crystallization behavior Dynamic condition High-oleic sunflower oil Polymorphic behavior Shear conditions Static conditions Tempering temperature Thermal behaviors Crystallization Morphology Oils and fats Textures Polymorphism Helianthus Soft (SS) and hard (HS) stearins obtained from high-oleic high-stearic sunflower oil were isothermally crystallized under dynamic (with agitation) and static conditions at 16, 17, 18, 19, and 20 C and 24, 25, 26, 27, and 28 C, respectively. Both fractions crystallized under the α-form at early stages of crystallization for all temperatures (T c) tested. Polymorphic behavior strongly changed with T c and shear conditions for both fractions. SS fractions were characterized by α, β2 and/or β1 polymorphs at lower T c and β1 crystals at higher T c when crystallized under dynamic conditions, while this same fat system was characterized by β2′ crystals at lower T c and β2 at higher T c under static conditions. HS samples were mainly characterized by α and β2 crystals at lower T c and α and β1 crystals at higher T c when crystallized under dynamic conditions; while the same fat was characterized by β 1′ crystals when crystallized at lower T c and α when crystallized at higher T c under static conditions after 90 min at T c. These different polymorphic behaviors, in combination with the different processing and tempering temperatures are translated in specific textural behavior of the samples. © 2013 AOCS. Fil:Candal, R.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2013 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0003021X_v90_n12_p1773_Martini http://hdl.handle.net/20.500.12110/paper_0003021X_v90_n12_p1773_Martini |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Crystallization Fats High stearic high oleic sunflower oil Morphology Polymorphism Texture Thermal behavior Crystallization behavior Dynamic condition High-oleic sunflower oil Polymorphic behavior Shear conditions Static conditions Tempering temperature Thermal behaviors Crystallization Morphology Oils and fats Textures Polymorphism Helianthus |
spellingShingle |
Crystallization Fats High stearic high oleic sunflower oil Morphology Polymorphism Texture Thermal behavior Crystallization behavior Dynamic condition High-oleic sunflower oil Polymorphic behavior Shear conditions Static conditions Tempering temperature Thermal behaviors Crystallization Morphology Oils and fats Textures Polymorphism Helianthus Candal, Roberto Jorge Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions |
topic_facet |
Crystallization Fats High stearic high oleic sunflower oil Morphology Polymorphism Texture Thermal behavior Crystallization behavior Dynamic condition High-oleic sunflower oil Polymorphic behavior Shear conditions Static conditions Tempering temperature Thermal behaviors Crystallization Morphology Oils and fats Textures Polymorphism Helianthus |
description |
Soft (SS) and hard (HS) stearins obtained from high-oleic high-stearic sunflower oil were isothermally crystallized under dynamic (with agitation) and static conditions at 16, 17, 18, 19, and 20 C and 24, 25, 26, 27, and 28 C, respectively. Both fractions crystallized under the α-form at early stages of crystallization for all temperatures (T c) tested. Polymorphic behavior strongly changed with T c and shear conditions for both fractions. SS fractions were characterized by α, β2 and/or β1 polymorphs at lower T c and β1 crystals at higher T c when crystallized under dynamic conditions, while this same fat system was characterized by β2′ crystals at lower T c and β2 at higher T c under static conditions. HS samples were mainly characterized by α and β2 crystals at lower T c and α and β1 crystals at higher T c when crystallized under dynamic conditions; while the same fat was characterized by β 1′ crystals when crystallized at lower T c and α when crystallized at higher T c under static conditions after 90 min at T c. These different polymorphic behaviors, in combination with the different processing and tempering temperatures are translated in specific textural behavior of the samples. © 2013 AOCS. |
author |
Candal, Roberto Jorge |
author_facet |
Candal, Roberto Jorge |
author_sort |
Candal, Roberto Jorge |
title |
Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions |
title_short |
Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions |
title_full |
Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions |
title_fullStr |
Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions |
title_full_unstemmed |
Crystallization Behavior of High-Oleic High-Stearic Sunflower Oil Stearins under Dynamic and Static Conditions |
title_sort |
crystallization behavior of high-oleic high-stearic sunflower oil stearins under dynamic and static conditions |
publishDate |
2013 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0003021X_v90_n12_p1773_Martini http://hdl.handle.net/20.500.12110/paper_0003021X_v90_n12_p1773_Martini |
work_keys_str_mv |
AT candalrobertojorge crystallizationbehaviorofhigholeichighstearicsunfloweroilstearinsunderdynamicandstaticconditions |
_version_ |
1768546046910136320 |