Dramatic Electronic Perturbations of Cu A Centers via Subtle Geometric Changes
Cu A is a binuclear copper site acting as electron entry port in terminal heme-copper oxidases. In the oxidized form, Cu A is a mixed valence pair whose electronic structure can be described using a potential energy surface with two minima, σ u ∗ and π u , that are variably populated at room tempera...
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2019
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v141_n3_p1373_Leguto http://hdl.handle.net/20.500.12110/paper_00027863_v141_n3_p1373_Leguto |
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