A surprisingly stable S-nitrosothiol complex

In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully...

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Detalles Bibliográficos
Autores principales: Perissinotti, Laura L., Estrin, Dario Ariel, Doctorovich, Fabio Ariel
Publicado: 2006
Materias:
s nitrosothiol
article
complex formation
crystal structure
density functional theory
infrared spectroscopy
proton nuclear magnetic resonance
synthesis
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00027863_v128_n8_p2512_Perissinotti
http://hdl.handle.net/20.500.12110/paper_00027863_v128_n8_p2512_Perissinotti
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully characterized by FTIR, 1H NMR, and ESI-MS. To our knowledge this is the first example of a coordinated S-nitrosothiol that has been isolated. Copyright © 2006 American Chemical Society.

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