First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB>
The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in...
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| Autores principales: | , , , |
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| Formato: | Articulo |
| Lenguaje: | Inglés |
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2000
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| Acceso en línea: | http://sedici.unlp.edu.ar/handle/10915/112677 https://ri.conicet.gov.ar/11336/53263 https://onlinelibrary.wiley.com/doi/abs/10.1002/1097-4555%28200010%2931%3A10%3C881%3A%3AAID-JRS588%3E3.0.CO%3B2-T |
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I19-R120-10915-112677 |
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dspace |
| institution |
Universidad Nacional de La Plata |
| institution_str |
I-19 |
| repository_str |
R-120 |
| collection |
SEDICI (UNLP) |
| language |
Inglés |
| topic |
Química Raman spectra Temperature |
| spellingShingle |
Química Raman spectra Temperature Romano, Rosana Mariel Della Védova, Carlos Omar Mora Valdez, M. I. Cutin, Edgardo Hugo First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB> |
| topic_facet |
Química Raman spectra Temperature |
| description |
The vibrational spectra, including Raman spectra at different temperatures and resonance Raman spectra, and theoretical calculations of N‐fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N= S(F)CF3, were obtained and interpreted. They point to the existence of a predominant anti–syn form and in equilibrium at lower concentration a syn–syn form (the first related to the nitrogen lone pair with respect to the sulfur lone pair and the second is related to the C= O double bond with respect to the N= S double bond). The general result indicates that it is the first anti configuration reported for this type of molecule implying for the energetically most favoured form an anti configuration of the lone pairs attached to both the S and N atoms. |
| format |
Articulo Articulo |
| author |
Romano, Rosana Mariel Della Védova, Carlos Omar Mora Valdez, M. I. Cutin, Edgardo Hugo |
| author_facet |
Romano, Rosana Mariel Della Védova, Carlos Omar Mora Valdez, M. I. Cutin, Edgardo Hugo |
| author_sort |
Romano, Rosana Mariel |
| title |
First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB> |
| title_short |
First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB> |
| title_full |
First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB> |
| title_fullStr |
First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB> |
| title_full_unstemmed |
First example of a preferred anti configuration in RN=SX<SUB>2</SUB> compounds: N-fluoroformyliminotrifluoromethylsulfur fluoride, FC(O)N=S(F)CF<SUB>3</SUB> |
| title_sort |
first example of a preferred anti configuration in rn=sx<sub>2</sub> compounds: n-fluoroformyliminotrifluoromethylsulfur fluoride, fc(o)n=s(f)cf<sub>3</sub> |
| publishDate |
2000 |
| url |
http://sedici.unlp.edu.ar/handle/10915/112677 https://ri.conicet.gov.ar/11336/53263 https://onlinelibrary.wiley.com/doi/abs/10.1002/1097-4555%28200010%2931%3A10%3C881%3A%3AAID-JRS588%3E3.0.CO%3B2-T |
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