Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate

The reaction of N-phenyl-1-(pyridin-2-yl)methanimine with copper chloride dihydrate produced the title neutral complex, [CuCl2(C12H10N2)(H2O)]·H2O. The CuII ion is five-coordinated in a distorted square-pyramidal geometry, in which the two N atoms of the bidentate Schiff base, as well as one chloro...

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Autores principales: Molano, Miguel F., Lorett Velasquez, Vaneza P., Erben, Mauricio Federico, Nossa González, Diana L., Loaiza, Alix E., Echeverría, Gustavo Alberto, Piro, Oscar Enrique, Tobón, Yeny A., Ben Tayeb, Karima, Gómez Castaño, Jovanny A.
Formato: Articulo
Lenguaje:Inglés
Publicado: 2020
Materias:
Química
Crystal structure
Copper(II)
Five-coordinate complexes
Distorted square pyramid
Acceso en línea:http://sedici.unlp.edu.ar/handle/10915/107841
http://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC7001833&blobtype=pdf
Aporte de:
SEDICI (UNLP) de Universidad Nacional de La Plata
id I19-R120-10915-107841
record_format dspace
institution Universidad Nacional de La Plata
institution_str I-19
repository_str R-120
collection SEDICI (UNLP)
language Inglés
topic Química
Crystal structure
Copper(II)
Five-coordinate complexes
Distorted square pyramid
spellingShingle Química
Crystal structure
Copper(II)
Five-coordinate complexes
Distorted square pyramid
Molano, Miguel F.
Lorett Velasquez, Vaneza P.
Erben, Mauricio Federico
Nossa González, Diana L.
Loaiza, Alix E.
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Tobón, Yeny A.
Ben Tayeb, Karima
Gómez Castaño, Jovanny A.
Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate
topic_facet Química
Crystal structure
Copper(II)
Five-coordinate complexes
Distorted square pyramid
description The reaction of N-phenyl-1-(pyridin-2-yl)methanimine with copper chloride dihydrate produced the title neutral complex, [CuCl2(C12H10N2)(H2O)]·H2O. The CuII ion is five-coordinated in a distorted square-pyramidal geometry, in which the two N atoms of the bidentate Schiff base, as well as one chloro and a water mol­ecule, form the irregular base of the pyramidal structure. Meanwhile, the apical chloride ligand inter­acts through a strong hydrogen bond with a water mol­ecule of crystallization. In the crystal, mol­ecules are arranged in pairs, forming a stacking of symmetrical cyclic dimers that inter­act in turn through strong hydrogen bonds between the chloride ligands and both the coordinated and the crystallization water mol­ecules. The mol­ecular and electronic structures of the complex were also studied in detail using EPR (continuous and pulsed), FT–IR and Raman spectroscopy, as well as magnetization measurements. Likewise, Hirshfeld surface analysis was used to investigate the inter­molecular inter­actions in the crystal packing.
format Articulo
Articulo
author Molano, Miguel F.
Lorett Velasquez, Vaneza P.
Erben, Mauricio Federico
Nossa González, Diana L.
Loaiza, Alix E.
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Tobón, Yeny A.
Ben Tayeb, Karima
Gómez Castaño, Jovanny A.
author_facet Molano, Miguel F.
Lorett Velasquez, Vaneza P.
Erben, Mauricio Federico
Nossa González, Diana L.
Loaiza, Alix E.
Echeverría, Gustavo Alberto
Piro, Oscar Enrique
Tobón, Yeny A.
Ben Tayeb, Karima
Gómez Castaño, Jovanny A.
author_sort Molano, Miguel F.
title Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate
title_short Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate
title_full Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate
title_fullStr Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate
title_full_unstemmed Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of aquadichlorido{N- [(pyridin-2-yl)methylidene]aniline}copper(II) monohydrate
title_sort crystal structure, spectroscopic characterization and hirshfeld surface analysis of aquadichlorido{n- [(pyridin-2-yl)methylidene]aniline}copper(ii) monohydrate
publishDate 2020
url http://sedici.unlp.edu.ar/handle/10915/107841
http://europepmc.org/backend/ptpmcrender.fcgi?accid=PMC7001833&blobtype=pdf
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