About the cure kinetics in natural rubber/styrene Butadiene rubber blends at 433 K
Vulcanized blends of elastomers are employed in several goods mainly to improve physical properties and reduce costs. One of the most used blends of this kind is that composed by natural rubber (NR) and styrene butadiene rubber (SBR). The cure kinetic of these blends depends mainly on the compound f...
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2012
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| 100 | 1 | |a Mansilla, Marcela Angela | |
| 245 | 1 | 6 | |a About the cure kinetics in natural rubber/styrene Butadiene rubber blends at 433 K |
| 260 | |c 2012 | ||
| 270 | 1 | 0 | |m Mansilla, M.A.; Laboratorio de Polímeros y Materiales Compuestos, Departamento de Física, Pabellón 1, C1428EGA Buenos Aires, Argentina; email: mmansilla@df.uba.ar |
| 504 | |a Mansilla, M.A., Ghiladucci, A., Salva, H., Marzocca, A.J., (2010) Proceeding IBEROMET XI, pp. 3-12 | ||
| 504 | |a Cunneen, J.I., Russell, R.M., (1970) Rubber Chem. Technol., 43, pp. 1215-1224 | ||
| 504 | |a Flory, P.J., Rehner, J., (1943) J. Chem. Phys., 11, pp. 521-526 | ||
| 504 | |a Gronski, W., Hoffmann, U., Simon, G., Wutzler, A., Straube, E., (1992) Rubber Chem. Technol., 65, pp. 63-77 | ||
| 504 | |a Marzocca, A.J., (2007) Eur. Polym. J., 43, pp. 2682-2689 | ||
| 504 | |a Kraus, K., (1957) Rubber Chem. Technol., 30, pp. 928-951 | ||
| 504 | |a Kamal, M.R., Sourour, S., (1973) Polym. Eng. Sci., 13, pp. 59-64 | ||
| 504 | |a Isayev, A.I., Deng, J.S., (1988) Rubber Chem. Technol., 61, pp. 340-361 | ||
| 504 | |a Chough, S.H., Chang, D.H., (1996) J. Appl Polym Sci., 61, pp. 449-454 | ||
| 504 | |a Strobl, G., (2007) The Physics of Polymer, , Third ed. Springer Berlin | ||
| 504 | |a Marzocca, A.J., Mansilla, M.A., (2006) J. Appl Polym Sci., 101, pp. 35-41 | ||
| 504 | |a Marzocca, A.J., Goyanes, S., (2004) J. Appl Polym Sci., 91, pp. 2601-2609 | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a Vulcanized blends of elastomers are employed in several goods mainly to improve physical properties and reduce costs. One of the most used blends of this kind is that composed by natural rubber (NR) and styrene butadiene rubber (SBR). The cure kinetic of these blends depends mainly on the compound formulation and the cure temperature and time. The preparation method of the blends can influence the mechanical properties of the vulcanized compounds. In this work the cure kinetic at 433 K of NR/SBR blends vulcanized with the system sulfur/TBBS (N-t-butyl-2-benzothiazole sulfenamide) is analyzed in samples prepared by mechanical mixing and solution blending. The two methods produce elastomer domains of NR and SBR, which present different microstructure due to the cure level attained during vulcanization. The cure kinetics is studied by means of rheometer tests and the model proposed by Kamal and Sourour. The analysis of the cure rate is presented and is related to the structure obtained during the vulcanization process. © 2011 Elsevier B.V. All rights reserved. |l eng | |
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: This work was supported by the University of Buenos Aires and CONICET, both from Argentina. | ||
| 593 | |a Laboratorio de Polímeros y Materiales Compuestos, Departamento de Física, Pabellón 1, C1428EGA Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a BLEND |
| 690 | 1 | 0 | |a CROSSLINKS |
| 690 | 1 | 0 | |a CURE KINETICS |
| 690 | 1 | 0 | |a NATURAL RUBBER |
| 690 | 1 | 0 | |a STYRENE BUTADIENE RUBBER |
| 690 | 1 | 0 | |a BLEND |
| 690 | 1 | 0 | |a BLENDS OF ELASTOMERS |
| 690 | 1 | 0 | |a BUTADIENE RUBBER |
| 690 | 1 | 0 | |a CROSSLINKS |
| 690 | 1 | 0 | |a CURE KINETICS |
| 690 | 1 | 0 | |a CURE RATE |
| 690 | 1 | 0 | |a CURE TEMPERATURE |
| 690 | 1 | 0 | |a MECHANICAL MIXING |
| 690 | 1 | 0 | |a PREPARATION METHOD |
| 690 | 1 | 0 | |a SOLUTION BLENDING |
| 690 | 1 | 0 | |a STYRENE BUTADIENE RUBBER |
| 690 | 1 | 0 | |a SULFENAMIDES |
| 690 | 1 | 0 | |a VULCANIZATION PROCESS |
| 690 | 1 | 0 | |a VULCANIZED COMPOUNDS |
| 690 | 1 | 0 | |a BLENDING |
| 690 | 1 | 0 | |a KINETICS |
| 690 | 1 | 0 | |a MECHANICAL PROPERTIES |
| 690 | 1 | 0 | |a POLYMER BLENDS |
| 690 | 1 | 0 | |a RUBBER |
| 690 | 1 | 0 | |a STYRENE |
| 690 | 1 | 0 | |a VULCANIZATION |
| 690 | 1 | 0 | |a CURING |
| 700 | 1 | |a Marzocca, Angel José | |
| 773 | 0 | |d 2012 |g v. 407 |h pp. 3271-3273 |k n. 16 |p Phys B Condens Matter |x 09214526 |w (AR-BaUEN)CENRE-279 |t Physica B: Condensed Matter | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-84862193039&doi=10.1016%2fj.physb.2011.12.084&partnerID=40&md5=4a837bddd5a11ca512870c91db8f0877 |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1016/j.physb.2011.12.084 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_09214526_v407_n16_p3271_Mansilla |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v407_n16_p3271_Mansilla |y Registro en la Biblioteca Digital |
| 961 | |a paper_09214526_v407_n16_p3271_Mansilla |b paper |c PE | ||
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