Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates

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The substituted hydroxylamines, CH 3 N(H)OH (N- methylhydroxylamine) and (CH 3 ) 2 NOH (N,N- dimethylhydroxylamine), disproportionate catalytically to the corresponding alkylamines and oxidation products, only in the presence of [Fe(CN) 5 H 2 O] 3- . Substitution kinetic measurements suggest an init...

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Autor principal: Gutiérrez, M.M
Otros Autores: Alluisetti, G.B, Olabe, J.A, Amorebieta, V.T
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: 2009
Acceso en línea:Registro en Scopus
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Biblioteca Central Dr. Luis F. Leloir (FCEN) de Universidad de Buenos Aires
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100 1 |a Gutiérrez, M.M. 
245 1 0 |a Catalytic disproportionation of N-alkylhydroxylamines bound to pentacyanoferrates 
260 |c 2009 
270 1 0 |m Amorebieta, V. T.; Department of Chemistry, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes y Roca, Mar del Plata B7602AYL, Argentina; email: amorebie@mdp.edu.ar 
506 |2 openaire  |e Política editorial 
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520 3 |a The substituted hydroxylamines, CH 3 N(H)OH (N- methylhydroxylamine) and (CH 3 ) 2 NOH (N,N- dimethylhydroxylamine), disproportionate catalytically to the corresponding alkylamines and oxidation products, only in the presence of [Fe(CN) 5 H 2 O] 3- . Substitution kinetic measurements suggest an initial coordination step to Fe(ii). Two parallel N- and O-coordination modes are considered with the subsequent formation of Fe(iii), free aminyl (RNCH 3 ) and nitroxide (RN(CH 3 )O) radicals (R = H, CH 3 ). With CH 3 N(H)OH, bound nitrosomethane, CH 3 NO, has been characterized by UV-visible and IR spectroscopies. The mechanism is discussed on the basis of common and differential features with respect to the disproportionation of hydroxylamine catalyzed by the same Fe-fragment. © The Royal Society of Chemistry 2009.  |l eng 
593 |a Department of Chemistry, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes y Roca, Mar del Plata B7602AYL, Argentina 
593 |a Department of Inorganic, Analytical and Physical Chemistry, INQUIMAE, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina 
690 1 0 |a AMINES 
690 1 0 |a IRON COMPOUNDS 
690 1 0 |a REACTION KINETICS 
690 1 0 |a ALKYL-AMINES 
690 1 0 |a COORDINATION MODES 
690 1 0 |a DISPROPORTIONATION 
690 1 0 |a IR SPECTROSCOPIES 
690 1 0 |a KINETIC MEASUREMENTS 
690 1 0 |a NITROXIDE 
690 1 0 |a OXIDATION PRODUCTS 
690 1 0 |a UV-VISIBLE 
690 1 0 |a SULFUR COMPOUNDS 
700 1 |a Alluisetti, G.B. 
700 1 |a Olabe, J.A. 
700 1 |a Amorebieta, V.T. 
773 0 |d 2009  |h pp. 1187-1194  |k n. 7  |p Dalton Trans.  |x 14779226  |t Dalton Transactions 
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856 4 0 |u https://doi.org/10.1039/b812173g  |y DOI 
856 4 0 |u https://hdl.handle.net/20.500.12110/paper_14779226_v_n7_p1187_Gutierrez  |y Handle 
856 4 0 |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v_n7_p1187_Gutierrez  |y Registro en la Biblioteca Digital 
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