Rhodotorula minuta-mediated bioreduction of 1,2-diketones
The reduction of cyclic and acyclic 1,2-diketones was investigated by employing whole cells of the yeast Rhodotorula minuta as biocatalyst. The reactions showed a variable degree of regio- and enantioselectivity depending on the nature of the substrate. In the case of cyclic diketones, the reduction...
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2010
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| LEADER | 10873caa a22011897a 4500 | ||
|---|---|---|---|
| 001 | PAPER-8059 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203751.0 | ||
| 008 | 190411s2010 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-77249083645 | |
| 024 | 7 | |2 cas |a 2,3 butanedione, 431-03-8 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a BOBOE | ||
| 100 | 1 | |a Monsalve, L.N. | |
| 245 | 1 | 0 | |a Rhodotorula minuta-mediated bioreduction of 1,2-diketones |
| 260 | |c 2010 | ||
| 270 | 1 | 0 | |m Baldessari, A.; Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, C1428EGA Buenos Aires, Argentina; email: alib@qo.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a The reduction of cyclic and acyclic 1,2-diketones was investigated by employing whole cells of the yeast Rhodotorula minuta as biocatalyst. The reactions showed a variable degree of regio- and enantioselectivity depending on the nature of the substrate. In the case of cyclic diketones, the reduction afforded a mixture of diastereomeric diols only. The reduction of acyclic diketones allowed production of both the hydroxy ketone and the diol, in a two-step reaction. The first step was highly regio- and stereoselective, affording the hydroxy ketone of (S)-configuration with high enantiomeric excess. After longer reaction times the corresponding (S,S)-diols were obtained in high yield and diastereomeric excess. © 2010 Informa UK Ltd. |l eng | |
| 536 | |a Detalles de la financiación: Agencia Nacional de Promoción Científica y Tecnológica, PICT 2005 06-32735 | ||
| 536 | |a Detalles de la financiación: We thank UBA (X089 (2004-2007) and X010 (2008-2010), ANPCyT (PICT 2005 06-32735) for partial financial support. A.B. and M.A.G. are Research Members of CONICET. The authors | ||
| 593 | |a Departamento de Química Orgánica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, C1428EGA Buenos Aires, Argentina | ||
| 593 | |a Departamento de Ingeniería Química, Facultad de Ingeniería, Universidad de Buenos Aires, Buenos Aires, Argentina | ||
| 593 | |a IIB-Intech-CONICET-UNSAM, Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a 1,2-DIKETONES |
| 690 | 1 | 0 | |a BIOREDUCTION |
| 690 | 1 | 0 | |a RHODOTORULA MINUTA |
| 690 | 1 | 0 | |a BIOREDUCTIONS |
| 690 | 1 | 0 | |a DIASTEREOMERIC |
| 690 | 1 | 0 | |a DIASTEREOMERIC EXCESS |
| 690 | 1 | 0 | |a DIKETONES |
| 690 | 1 | 0 | |a ENANTIOMERIC EXCESS |
| 690 | 1 | 0 | |a HIGH YIELD |
| 690 | 1 | 0 | |a REACTION TIME |
| 690 | 1 | 0 | |a STEREO-SELECTIVE |
| 690 | 1 | 0 | |a TWO-STEP REACTIONS |
| 690 | 1 | 0 | |a WHOLE CELL |
| 690 | 1 | 0 | |a ENANTIOSELECTIVITY |
| 690 | 1 | 0 | |a KETONES |
| 690 | 1 | 0 | |a 1,2 CYCLOHEXANEDIOL DERIVATIVE |
| 690 | 1 | 0 | |a 1,2 DIKETONE DERIVATIVE |
| 690 | 1 | 0 | |a 2 PHENYL 2,3 PROPANEDIONE |
| 690 | 1 | 0 | |a 2,3 BUTANEDIONE |
| 690 | 1 | 0 | |a 2,3 PENTANEDIONE |
| 690 | 1 | 0 | |a DIKETONE |
| 690 | 1 | 0 | |a UNCLASSIFIED DRUG |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CONTROLLED STUDY |
| 690 | 1 | 0 | |a ENANTIOMER |
| 690 | 1 | 0 | |a ENANTIOSELECTIVITY |
| 690 | 1 | 0 | |a GAS LIQUID CHROMATOGRAPHY |
| 690 | 1 | 0 | |a NONHUMAN |
| 690 | 1 | 0 | |a REDUCTION |
| 690 | 1 | 0 | |a RHODOTORULA |
| 690 | 1 | 0 | |a RHODOTORULA MINUTA |
| 690 | 1 | 0 | |a STEREOCHEMISTRY |
| 690 | 1 | 0 | |a RHODOTORULA MINUTA |
| 700 | 1 | |a Cerrutti, P. | |
| 700 | 1 | |a Galvagno, M.A. | |
| 700 | 1 | |a Baldessari, A. | |
| 773 | 0 | |d 2010 |g v. 28 |h pp. 137-143 |k n. 2 |p Biocatal. Biotransform. |x 10242422 |w (AR-BaUEN)CENRE-3908 |t Biocatalysis and Biotransformation | |
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| 856 | 4 | 0 | |u https://doi.org/10.3109/10242420903515445 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_10242422_v28_n2_p137_Monsalve |y Handle |
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