Near-critical and supercritical dilute solutions viewed from macroscopic and molecular-scale perspectives
Partial molar properties of dilute solutes in near-critical solvents exhibit a strong dependence on temperature and density which hinders the description of their behaviour under those conditions. We used the well-behaved Krichevskii function, J = (dp/dx)V,T supra infinity, to describe that region o...
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2010
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| LEADER | 13974caa a22012137a 4500 | ||
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| 003 | AR-BaUEN | ||
| 005 | 20230518203714.0 | ||
| 008 | 190411s2010 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-78649795147 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a JSFLE | ||
| 100 | 1 | |a Fernández-Prini, R. | |
| 245 | 1 | 0 | |a Near-critical and supercritical dilute solutions viewed from macroscopic and molecular-scale perspectives |
| 260 | |c 2010 | ||
| 270 | 1 | 0 | |m Fernández-Prini, R.; Gerencia Química, Comisión Nacional de Energía Atómica, Av. Libertador 8250, 1429 Buenos Aires, Argentina; email: rfprini@cnea.gov.ar |
| 506 | |2 openaire |e Política editorial | ||
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| 520 | 3 | |a Partial molar properties of dilute solutes in near-critical solvents exhibit a strong dependence on temperature and density which hinders the description of their behaviour under those conditions. We used the well-behaved Krichevskii function, J = (dp/dx)V,T supra infinity, to describe that region of the thermodynamic space, and have extended its use to ternary solutions (two solutes + one near-critical solvent) successfully. The use of supercritical solvents permits a controlled and continuous exploration of the density dependence of solutes' properties without undergoing phase transitions, hence the availability of a non-diverging property like J to describe the systems is greatly important. We show its application for binary and ternary systems that have been studied and also give some information about the molecular structure of near-critical solutions. This knowledge provides a better understanding about solvation and its dependence on long-range (critical) fluctuations in the presence of intermolecular interactions. © 2010 Published by Elsevier B.V. |l eng | |
| 536 | |a Detalles de la financiación: Secretaría de Ciencia y Técnica, Universidad de Buenos Aires, X128-X330 | ||
| 536 | |a Detalles de la financiación: EM and RFP thank partial financial support from UBACyT X128-X330. We thank Dionysis Foustoukos for providing the complete data set from Ref. [29] , as shown in Fig. 2 . EM and RFP are members of the Carrera del Investigador, CONICET (Argentina). | ||
| 593 | |a INQUIMAE/DQIAQF, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, 1428 Buenos Aires, Argentina | ||
| 593 | |a Gerencia Química, Comisión Nacional de Energía Atómica, Av. Libertador 8250, 1429 Buenos Aires, Argentina | ||
| 593 | |a Escuela de Ciencia y Tecnología, Universidad Nacional de San Martín, Martín de Irigoyen 3100, 1650 San Martín, Prov. Buenos Aires, Argentina | ||
| 690 | 1 | 0 | |a CRITICAL BEHAVIOUR |
| 690 | 1 | 0 | |a INTERMOLECULAR INTERACTIONS |
| 690 | 1 | 0 | |a KRICHEVSKII'S FUNCTION |
| 690 | 1 | 0 | |a NEAR-CRITICAL SOLVENTS |
| 690 | 1 | 0 | |a SOLVATION |
| 690 | 1 | 0 | |a CONTINUOUS EXPLORATION |
| 690 | 1 | 0 | |a CRITICAL BEHAVIOUR |
| 690 | 1 | 0 | |a CRITICAL SOLUTION |
| 690 | 1 | 0 | |a DENSITY DEPENDENCE |
| 690 | 1 | 0 | |a DILUTE SOLUTION |
| 690 | 1 | 0 | |a INTERMOLECULAR INTERACTIONS |
| 690 | 1 | 0 | |a KRICHEVSKII'S FUNCTION |
| 690 | 1 | 0 | |a NEAR-CRITICAL SOLVENTS |
| 690 | 1 | 0 | |a PARTIAL MOLAR PROPERTIES |
| 690 | 1 | 0 | |a SUPER-CRITICAL |
| 690 | 1 | 0 | |a SUPERCRITICAL SOLVENTS |
| 690 | 1 | 0 | |a TERNARY SOLUTION |
| 690 | 1 | 0 | |a PHASE TRANSITIONS |
| 690 | 1 | 0 | |a SOLVATION |
| 690 | 1 | 0 | |a TERNARY SYSTEMS |
| 690 | 1 | 0 | |a SOLVENTS |
| 700 | 1 | |a Laura Japas, M. | |
| 700 | 1 | |a Marceca, E. | |
| 773 | 0 | |d 2010 |g v. 55 |h pp. 472-478 |k n. 2 |p J. Supercritical Fluids |x 08968446 |w (AR-BaUEN)CENRE-5809 |t Journal of Supercritical Fluids | |
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