Vulcanization kinetic of styrene-butadiene rubber by sulfur/TBBS
Torque curves, measured with a moving die rheometer at temperatures between 413 and 473 K, were used to characterize the vulcanization of styrene-butadiene rubber with different cure systems based on sulfur and TBBS (N-t-butyl-2-benzothiazole sulfenamide). Several compounds were prepared varying the...
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2006
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 05034caa a22008177a 4500 | ||
|---|---|---|---|
| 001 | PAPER-7092 | ||
| 003 | AR-BaUEN | ||
| 005 | 20250723105757.0 | ||
| 008 | 190411s2006 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-33745177342 | |
| 030 | |a JAPNA | ||
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Marzocca, Angel José | |
| 245 | 1 | 0 | |a Vulcanization kinetic of styrene-butadiene rubber by sulfur/TBBS |
| 260 | |c 2006 | ||
| 270 | 1 | 0 | |m Marzocca, A.J.; Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, LPMPyMC, Pabellón 1, Buenos Aires (1428), Argentina; email: marzo@df.uba.ar |
| 504 | |a Coran, A.Y., (1994) Science and Technology of Rubber, p. 339. , Mark, J. E.; Erman, B.; Eirich, F. R., Eds.; Academic Press: San Diego | ||
| 504 | |a Ding, R., Leonov, A.I., (1996) J Appl Pol Sci, 61, p. 455 | ||
| 504 | |a Ding, R., Leonov, A.I., Coran, A.Y., (1996) Rubber Chem Tech, 69, p. 81 | ||
| 504 | |a Ghosh, P., Katare, S., Patkar, P., Caruthers, J., Venkatasubramanian, V., Walker, K.A., (2003) Rubber Chem Tech, 76, p. 592 | ||
| 504 | |a Kamal, M.R., Sourour, S., (1973) Polym Eng Sci, 13, p. 59 | ||
| 504 | |a Isayev, A.I., Deng, J.S., (1988) Rubber Chem Tech, 61, p. 340 | ||
| 504 | |a Deng, J.S., Isayev, A.I., (1991) Rubber Chem Tech, 64, p. 296 | ||
| 504 | |a Marzocca, A.J., Cerveny, S., Raimondo, R.B., (1997) J Appl Pol Sci, 66, p. 1085 | ||
| 504 | |a Cerveny, S., Marzocca, A.J., (1999) J Appl Pol Sci, 74, p. 2747 | ||
| 504 | |a Marzocca, A.J., Goyanes, S., (2004) J Appl Pol Sci, 91, p. 2601 | ||
| 504 | |a Marzocca, A.J., Goyanes, S., (2004) J Appl Pol Sci, 91, p. 4110 | ||
| 504 | |a Salgueiro, W., Marzocca, A., Somoza, A., Consolati, G., Cerveny, S., Quasso, F., Goyanes, S., (2004) Polymer, 45, p. 6037 | ||
| 504 | |a Marzocca, A.J., Cerveny, S., Mendez, J.M., (2000) Polym Int, 49, p. 216 | ||
| 504 | |a Marzocca, A.J., (2003) Proceedings Jomadas SAM-CONAMET, p. 10. , www.notimat.org.br/simposio2003/Trabajos/A10/1018.PDF, Simposio Materia, Bariloche, Argentina | ||
| 504 | |a Youssef, M.H., (2003) Polym Test, 22, p. 235 | ||
| 504 | |a Abd-El-Messieh, S.L., Abd-El-Nour, K.N., (2003) J Appl Polym Sci, 88, p. 1613 | ||
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a Torque curves, measured with a moving die rheometer at temperatures between 413 and 473 K, were used to characterize the vulcanization of styrene-butadiene rubber with different cure systems based on sulfur and TBBS (N-t-butyl-2-benzothiazole sulfenamide). Several compounds were prepared varying the amount of sulfur and accelerator between 0.5 and 2.5 phr in the formulation. By means of normalized torque curves, the kinetic of cure of these samples was evaluated considering the model of isothermal curing proposed by Kamal and Sourour. In this frame, the parameters of the kinetic model were obtained. The effect of the amount of sulfur and accelerator in the compound on the kinetic parameters was investigated and a maximum of the rate parameter k for the compound with formulation with 1.0 phr of sulfur and 2.0 phr of accelerator was found. A marked decrease in the activation energy of the cure process of the elastomer was observed at higher levels of TBBS in the compound. © 2006 Wiley Periodicals, Inc. |l eng | |
| 593 | |a Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, LPMPyMC, Pabellón 1, Buenos Aires (1428), Argentina | ||
| 690 | 1 | 0 | |a ACTIVATION ENERGY |
| 690 | 1 | 0 | |a CURE REACTION |
| 690 | 1 | 0 | |a KINETICS |
| 690 | 1 | 0 | |a STYRENE-BUTADIENE RUBBER |
| 690 | 1 | 0 | |a VULCANIZATION |
| 690 | 1 | 0 | |a ACTIVATION ENERGY |
| 690 | 1 | 0 | |a BUTADIENE |
| 690 | 1 | 0 | |a ELASTOMERS |
| 690 | 1 | 0 | |a REACTION KINETICS |
| 690 | 1 | 0 | |a RHEOMETERS |
| 690 | 1 | 0 | |a RUBBER |
| 690 | 1 | 0 | |a SULFUR |
| 690 | 1 | 0 | |a TORQUE CONTROL |
| 690 | 1 | 0 | |a VULCANIZATION |
| 690 | 1 | 0 | |a CURE SYSTEMS |
| 690 | 1 | 0 | |a ISOTHERMAL CURING |
| 690 | 1 | 0 | |a KINETIC PARAMETERS |
| 690 | 1 | 0 | |a TORQUE CURVES |
| 690 | 1 | 0 | |a STYRENE |
| 690 | 1 | 0 | |a ELASTOMER |
| 690 | 1 | 0 | |a KINETICS |
| 690 | 1 | 0 | |a POLYBUTADIENE |
| 690 | 1 | 0 | |a POLYSTYRENE |
| 690 | 1 | 0 | |a SYNTHETIC RUBBER |
| 690 | 1 | 0 | |a TEMPERATURE EFFECT |
| 690 | 1 | 0 | |a TORQUE |
| 700 | 1 | |a Mansilla, Marcela Angela | |
| 773 | 0 | |d 2006 |g v. 101 |h pp. 35-41 |k n. 1 |p J. Appl. Polym. Sci. |x 00218995 |w (AR-BaUEN)CENRE-330 |t Journal of Applied Polymer Science | |
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| 856 | 4 | 0 | |u https://doi.org/10.1002/app.23173 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00218995_v101_n1_p35_Marzocca |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v101_n1_p35_Marzocca |y Registro en la Biblioteca Digital |
| 961 | |a paper_00218995_v101_n1_p35_Marzocca |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 963 | |a VARI | ||
| 999 | |c 68045 | ||