Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series
Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate lig...
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| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
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Elsevier S.A.
2000
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
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| LEADER | 06591caa a22008657a 4500 | ||
|---|---|---|---|
| 001 | PAPER-20907 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518205220.0 | ||
| 008 | 190411s2000 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-0034732793 | |
| 024 | 7 | |2 cas |a acetoacetic acid, 541-50-4, 623-58-5; europium, 7440-53-1; gadolinium, 7440-54-2 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 030 | |a ICHAA | ||
| 100 | 1 | |a Aramendia, P.F. | |
| 245 | 1 | 0 | |a Novel europium and gadolinium compounds in the lanthanide(III) oxydiacetate series |
| 260 | |b Elsevier S.A. |c 2000 | ||
| 270 | 1 | 0 | |m Perec, M.; Departamento de Quimica Inorganica, Analitica y Quimica Fisica, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina; email: perec@q1.fcen.uba.ar |
| 506 | |2 openaire |e Política editorial | ||
| 504 | |a Choppin, G.R., (1989), J.-C.G. Bunzli, G.R. Choppin (Eds.), Lanthanide Probes in Life, Chemical and Earth Sciences, Elsevier, Amsterdam, Ch. 1; Parker, D., Williams, J.A.G., (1996) J. Chem. Soc., Dalton Trans., p. 3613 | ||
| 504 | |a Segal, D., (1989), Chemical Synthesis of Advanced Ceramic Material, Cambridge University Press, UK; Chanaud, P., Julbe, A., Vaija, P., Persin, M., Cot, L., (1994) J. Mater. Sci., 29, p. 4244 | ||
| 504 | |a Wang, S., Pang, Z., Smith, K.D.L., Wagner, M.J., (1994) J. Chem. Soc., Dalton Trans., p. 955 | ||
| 504 | |a Courty, P., Ajot, H., Marcilly, Ch., Delmon, B., (1973) Powder Technol., 7, p. 21 | ||
| 504 | |a Piguet, C., Bunzli, J.-C.G., Bernardinelli, G., Hopfgartner, G., Williams, A.F., (1995) J. Alloys Compd., 225, p. 324 | ||
| 504 | |a Alexander, V., (1995) Chem. Rev., 95, p. 273 | ||
| 504 | |a Yukawa, Y., Igarashi, S., Kawaura, T., Miyamoto, H., (1996) Inorg. Chem., 35, p. 7399 | ||
| 504 | |a Albertsson, J., Elding, I., (1976) Acta Crystallogr., 32 (Sect. B), p. 3066 | ||
| 504 | |a Elding, I., (1976) Acta Chem. Scand., 30 (Ser. A), p. 649 | ||
| 504 | |a Albertsson, J., Elding, I., (1977) Acta Chem. Scand., 31 (Ser. A), p. 21 | ||
| 504 | |a Albertsson, J., (1970) Acta Chem. Scand., 24, p. 3527 | ||
| 504 | |a Fronczek, F.R., Banerjee, A.K., Watkins, S.F., Schwartz, R.W., (1981) Inorg. Chem., 20, p. 2745 | ||
| 504 | |a Albin, M., Whittle, R.R., Horrocks W.R., Jr., (1985) Inorg. Chem., 24, p. 4591 | ||
| 504 | |a Albertsson, J., (1968) Acta Chem. Scand., 22, p. 1563 | ||
| 504 | |a Baggio, R., Garland, M.T., Perec, M., Vega, D., (1996) Inorg. Chem., 35, p. 2396 | ||
| 504 | |a Baggio, R., Garland, M.T., Perec, M., (1998) Inorg. Chim. Acta, 281, p. 18 | ||
| 504 | |a Elding, I., (1977) Acta Chem. Scand., Ser. A, 31, p. 75 | ||
| 504 | |a (1992), The JCPDS International Center for Diffraction Data, Swarthmore, PA, Powder Diffraction File No. 34-392 (Eu2O3) and No. 12-0797 (Gd2O3); Sheldrick, G.M., (1997), SHELXL-97, Program for Crystal Structure Refinement, University of Gottingen, Germany; Sheldrick, G.M., (1991), SHELXTL-PC. Version 4.2, Siemens Analytical X-ray Instruments Inc., Madison, WI; Nardelli, M., (1983) Comput. Chem., 7, p. 95 | ||
| 504 | |a Orpen, A.G., Brammer, L., Allen, F.H., Kennard, O., Watson, D.G., Taylor, R., (1989) J. Chem. Soc., Dalton Trans., pp. S1 | ||
| 504 | |a Baggio, R., Garland, M.T., Perec, M., (1997) Inorg. Chem., 36, p. 950 | ||
| 504 | |a Balzani, V., Sabbatini, N., Scandola, F., (1986) Chem. Rev., 86, p. 319 | ||
| 520 | 3 | |a Three new lanthanide oxydiacetate compounds have been prepared and their structures determined by single crystal X-ray methods: {[Ln2(oda)3(H2O)2]·5H2O}(n) (Ln = Eu, Gd) and [Eu(oda)(Hoda)(H2O)]·2H2O. The former are orthorhombic and Ama2, with LnO8 and LnO9 cores bridged by anti-anti carboxylate ligands and the latter is mononuclear containing a EuO9 core. Luminescence spectra of the europium complexes in the solid state are presented. (C) 2000 Elsevier Science S.A. |l eng | |
| 536 | |a Detalles de la financiación: Fondo Nacional de Desarrollo Científico, Tecnológico y de Innovación Tecnológica, 1981027 | ||
| 536 | |a Detalles de la financiación: Volkswagen Foundation | ||
| 536 | |a Detalles de la financiación: Universidad de Buenos Aires | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: Consejo Nacional de Investigaciones Científicas y Técnicas | ||
| 536 | |a Detalles de la financiación: This work was supported by the Universidad de Buenos Aires, by the Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET) and Proyecto FONDECYT No. 1981027. P.F.A. and M.P. are members of CONICET. We thank the Spanish Research Council (CSIC) for providing a free-of-charge license to the CSD system. P.F.A. thanks Volkswagen Foundation for a research grant. We thank Miss A. Petragalli for the TGA measurements. | ||
| 593 | |a Departamento de Química Inorgánica, Analítica y Química Física, Ciudad Universitaria, Pabellón II, 1428 Buenos Aires, Argentina | ||
| 593 | |a Departamento de Física, Comisión Nacional de Energía Atómica, Avda. del Libertador 8250, 1429 Buenos Aires, Argentina | ||
| 593 | |a Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Avda. Blanco Encalada 2008, Santiago, Chile | ||
| 690 | 1 | 0 | |a CRYSTAL STRUCTURES |
| 690 | 1 | 0 | |a LANTHANIDE COMPLEXES |
| 690 | 1 | 0 | |a LUMINESCENCE |
| 690 | 1 | 0 | |a ACETOACETIC ACID |
| 690 | 1 | 0 | |a EUROPIUM |
| 690 | 1 | 0 | |a GADOLINIUM |
| 690 | 1 | 0 | |a LANTHANIDE |
| 690 | 1 | 0 | |a ARTICLE |
| 690 | 1 | 0 | |a CHEMICAL STRUCTURE |
| 690 | 1 | 0 | |a CRYSTAL STRUCTURE |
| 690 | 1 | 0 | |a LIGAND BINDING |
| 690 | 1 | 0 | |a LUMINESCENCE |
| 690 | 1 | 0 | |a SOLID STATE |
| 690 | 1 | 0 | |a X RAY ANALYSIS |
| 700 | 1 | |a Baggio, R. | |
| 700 | 1 | |a Garland, M.T. | |
| 700 | 1 | |a Perec, M. | |
| 773 | 0 | |d Elsevier S.A., 2000 |g v. 303 |h pp. 306-310 |k n. 2 |p Inorg. Chim. Acta |x 00201693 |w (AR-BaUEN)CENRE-31 |t Inorganica Chimica Acta | |
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| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00201693_v303_n2_p306_Aramendia |y Handle |
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| 961 | |a paper_00201693_v303_n2_p306_Aramendia |b paper |c PE | ||
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