Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes

Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O.

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Detalles Bibliográficos
Autor principal: Nudelman, N.
Otros Autores: Schulz, H.
Formato: Capítulo de libro
Lenguaje:Inglés
Publicado: Royal Society of Chemistry 1999
Acceso en línea:Registro en Scopus
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Registro en la Biblioteca Digital
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100 1 |a Nudelman, N. 
245 1 0 |a Synthesis of highly hindered 1,2-diaryl diketones and of cis- and trans-1,2-diacetoxy-1,2-bis(aryl)ethenes 
260 |b Royal Society of Chemistry  |c 1999 
270 1 0 |m Nudelman, N.; Departamento de Quimica Organica, Facultad Ciencias Exactas Naturales, Universidad de Buenos Aires, Pab. II, P. 3, C. Universitaria, 1428 Buenos Aires, Argentina 
506 |2 openaire  |e Política editorial 
504 |a Trost, B.M., Fleming, I., (1993) Comprehensive Organic Synthesis, , Pergamon Press, New York, ch. 9 
504 |a Wirth, T., (1996) Angew. Chem., Int. Ed. Engl., 35, p. 61 
504 |a Tomaselli, G.A., Failla, S., Ballisteri, F.P., (1988) J. Org. Chem., 53, p. 830 
504 |a Karaman, R., Fry, J., (1989) Tetrahedron Lett., 30, p. 2757 
504 |a Katritzky, A.R., Wang, Z., Lang, H., Feng, D., (1997) J. Org. Chem., 62, p. 4125 
504 |a Kohler, E.P., Baltzly, R., (1932) J. Am. Chem. Soc., 54, p. 4015 
504 |a Nudelman, N.S., Doctorovich, F., (1994) Tetrahedron, 50, p. 4651 
504 |a Seyferth, D., Weinstein, R., (1982) J. Am. Chem. Soc., 104, p. 5534. , or thioesters 
504 |a Seyferth, D., Hul, R., (1984) Organometallics, 3, p. 327 
504 |a Schleyer, P.V.R., Winchester, W.R., Bauer, W., (1987) Organometallics, 6, p. 2371 
504 |a note; Nudelman, N.S., Vitale, A.A., (1983) J. Organomet. Chem., 241, p. 143 
504 |a Toda, F., (1995) Acc. Chem. Res., 28, p. 480 
504 |a Nudelman, N.S., Vitale, A.A., (1981) Org. Prep. Proced., 13, p. 144 
504 |a Nudelman, N.S., Lewcowicz, E.S., Perez, D.G., (1990) Synthesis, p. 917 
504 |a Fuson, R.C., Scott, S.L., Horning, E.C., McKeever, C., (1940) J. Am. Chem. Soc., 62, p. 2091 
504 |a Shacklett, C.D., Smieth, H.A., (1953) J. Am. Chem. Soc., 75, p. 2654 
504 |a Cook, J.W., (1930) J. Chem. Soc., p. 1087 
504 |a Fuson, R.C., McKeever, C.H., Corse, J., (1940) J. Am. Chem. Soc., 72, p. 600 
520 3 |a Highly hindered 1,2-diaryl diketones can be synthesized in good yields by the reaction of 1-aryllithium with CO in THF solution at atmospheric pressure; preparation of cis- and trans-1,2-diacetoxy-1,2-bis(Mes)ethene can be also afforded by a similar procedure and further quenching with Ac2O.  |l eng 
593 |a Depto. de Quim. Orgánica, Fac. de Ciencias Exactes y Naturales, Universidad de Buenos Aires, Pab. II, P. 3, 1428 Buenos Aires, Argentina 
690 1 0 |a 1,2 DICARBONYL DERIVATIVE 
690 1 0 |a CARBON MONOXIDE 
690 1 0 |a ETHYLENE DERIVATIVE 
690 1 0 |a LITHIUM DERIVATIVE 
690 1 0 |a ARTICLE 
690 1 0 |a CIS TRANS ISOMERISM 
690 1 0 |a CROSS LINKING 
690 1 0 |a STEREOSPECIFICITY 
690 1 0 |a SYNTHESIS 
700 1 |a Schulz, H. 
773 0 |d Royal Society of Chemistry, 1999  |h pp. 422-423  |k n. 7  |p J. Chem. Res. Part S  |x 03082342  |w (AR-BaUEN)CENRE-2560  |t Journal of Chemical Research - Part S 
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