Pressure dependence of the methyl radical combination reaction
The effect of pressure on the methyl radical combination reaction was measured following the pressure dependence of the cross-combination reaction for methyl-ethyl or methyl-isopropyl pairs of radicals. These were produced by the photolysis of the corresponding azo-compounds. The method was found to...
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| Otros Autores: | , |
| Formato: | Capítulo de libro |
| Lenguaje: | Inglés |
| Publicado: |
1968
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| Acceso en línea: | Registro en Scopus DOI Handle Registro en la Biblioteca Digital |
| Aporte de: | Registro referencial: Solicitar el recurso aquí |
| LEADER | 02297caa a22003137a 4500 | ||
|---|---|---|---|
| 001 | PAPER-1612 | ||
| 003 | AR-BaUEN | ||
| 005 | 20230518203058.0 | ||
| 008 | 190411s1968 xx ||||fo|||| 00| 0 eng|d | ||
| 024 | 7 | |2 scopus |a 2-s2.0-37049125407 | |
| 040 | |a Scopus |b spa |c AR-BaUEN |d AR-BaUEN | ||
| 100 | 1 | |a Grotewold, J. | |
| 245 | 1 | 0 | |a Pressure dependence of the methyl radical combination reaction |
| 260 | |c 1968 | ||
| 270 | 1 | 0 | |m Grotewold, J.; Universidad Tecnica del Estado, Laboratorio Central de Quimica, Casilla 4587, Santiago, Chile |
| 506 | |2 openaire |e Política editorial | ||
| 520 | 3 | |a The effect of pressure on the methyl radical combination reaction was measured following the pressure dependence of the cross-combination reaction for methyl-ethyl or methyl-isopropyl pairs of radicals. These were produced by the photolysis of the corresponding azo-compounds. The method was found to be very suitable for this type of study and 'fall-off' curves at 15, 60, and 100° were determined. In the range of pressures studied (from a few torr to 0·005 torr) the kuni/k∞ ratio varied from 1·0 to 0·25. The results do not support a loose activated complex model for the methyl radical combination reaction. |l eng | |
| 593 | |a Departamento de Quimica Inorganica, Anatitica y Quimica Fisica, Facultad de Ciencias Exactas y Naturales, Buenos Aires, Argentina | ||
| 593 | |a Universidad Tecnica del Estado, Laboratorio Central de Quimica, Casilla 4587, Santiago, Chile | ||
| 700 | 1 | |a Lissi, E.A. | |
| 700 | 1 | |a Neumann, M.G. | |
| 773 | 0 | |d 1968 |h pp. 375-381 |x 00224944 |t Journal of the Chemical Society A: Inorganic, Physical, Theoretical | |
| 856 | 4 | 1 | |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-37049125407&doi=10.1039%2fJ19680000375&partnerID=40&md5=195e4e15ec5e924bb8d08e7c8e9becef |y Registro en Scopus |
| 856 | 4 | 0 | |u https://doi.org/10.1039/J19680000375 |y DOI |
| 856 | 4 | 0 | |u https://hdl.handle.net/20.500.12110/paper_00224944_v_n_p375_Grotewold |y Handle |
| 856 | 4 | 0 | |u https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00224944_v_n_p375_Grotewold |y Registro en la Biblioteca Digital |
| 961 | |a paper_00224944_v_n_p375_Grotewold |b paper |c PE | ||
| 962 | |a info:eu-repo/semantics/article |a info:ar-repo/semantics/artículo |b info:eu-repo/semantics/publishedVersion | ||
| 999 | |c 62565 | ||